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Maintenance of the moisture sensor

The most common type of moisture sensor used in glove boxes has a probe head covered with a layer of phosphoric acid. The phosphoric acid deteriorates over time, which is why it needs to be renewed regularly (approximately every 2,000 hours). One of the manufacturers has created an instructional video (external link) on how to do this. In short, the phosphoric acid must be rinsed off with distilled water. Then, after drying the probe head, it is impregnated again with new phosphoric acid.

How does it work?

The principle behind this sensor is based on the fact that P2O5 is extremely hygroscopic - one of the most hygroscopic substances there is. This means that all the moisture is basically absolutely absorbed into. P2O5 then forms polyphosphoric acids with water until phosphoric acid (H3PO4) is reached. Therefore the probe head (Figure 1) is impregnated with phosphoric acid.

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Figure 1: Probe head of of a phosphoric acid-based moisture sensor. The thin traces are elektrodes made from platinum.
Figure 2: Schematic display of the working principle of a phosphoric acid-based moisture sensor.